The gray PVC conduit that Bob speaks of is sunlight resistant, so that is what you should use. It comes in 10' joints. 2" will have plenty of room for two 4/0 cables, even cable with thick insulation. You can get 2" terminal adapters which will glue on and have threads on the end. You can then get 2" plastic bushings which screw on the threads to avoid having a sharp edge which might cut the insulation over time. All these materials are available from any electrical supply house. Plenty of boats have chases built in that serve the same function as the PVC conduit, there is no reason you can't do this.